That’s why I took part in Ginger Stache’s documentary, “Before You Say Good-bye.” The documentary aired nationwide and in Europe resulting in my talented boss being nominated for two regional Emmys for the half-hour film. Eventually, I graduated from college, and later began working in the broadcasting field. I gave my life to Jesus on that same psychiatric ward and started living a different lifestyle by reading the Bible, attending church and recovery meetings, finding freedom from drugs and alcohol, exercising, eating right, and waiting on God’s intervention by praying instead of reacting from pain or panic.ĭepression and shame about the stigma of mental illness gave way to the gradual understanding that my testimony offered hope to others still hurting. ![]() My healing and faith journey began after learning people and circumstances can break our hearts, but that God’s heart is also broken when His children suffer. Before the pastor’s reassurance of our heavenly Father’s concern, I had never felt loved by God wondering why He didn’t protect me when I needed His help most. I didn’t realize God cared and understood the pain I felt as a frightened child living in an alcoholic home afraid to sleep at night. This supernatural knowledge changed my perception of our Creator. A pastor visited me there and explained, “What happened to you as a child, hurt God more than it hurt you.” Instead of fulfilling this dire prophecy, over three decades ago, I found emotional and spiritual healing on a psychiatric ward the last time I had to be hospitalized. Back then, little had been accomplished in mental health reform, and the hospital was a barbaric place not offering any real hope for recovery.Īs the years passed, following a couple more serious suicide attempts, an ongoing battle with addiction, along with intermittent and lengthy hospitalizations, a psychiatrist in charge of my case said I would probably die by suicide or in a mental institution. Months later, I would spend much of my senior year in Toledo State Mental Hospital. ![]() I recovered physically, but not emotionally. Only a high school junior, my hopeless and unstable environment resulted in the near fatal, intentional drug overdose, which landed me in an Intensive Care Unit hovering between life and death. My story begins during the 1970s, when as a depressed teenager living in a dysfunctional home I attempted suicide. I agreed to be interviewed for her project. It was during the late 1990s, when Ginger Stache, my former supervisor, who is an award-winning journalist, decided to create awareness about suicide by producing a documentary. Despite this, with the catalyst of educating others, I started to tell my story publicly while working as a reporter and producer at Lima’s WTLW TV 44. ![]() Yet sharing about a mental health struggle can feel shameful and frightening.
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Worksheets are the basis for all of Visual Analytics charts and views. The Menu allows creating a new Workbook, opening an existing Workbook, saving the current Workbook, saving as, exporting as a Packaged Workbook and closing the current Workbook.Ī list of recently opened workbooks appears underneath the menu item to make finding and opening your previous work easy.įor pulling in and extracting data, the Menu allows you to connect to data, take action on the data sources you've already established, and refresh all of the extracts for your current Workbook. ![]() The Menu contains the, ,, , and menus. Show Data Labels - Display Data Labels in the chartĬhart Fit Drop Down - Resize charts to display information in Standard, Fit Height, Fit Width or Entire View mode. Sort Descending - Sort data in the descending order Sort Ascending - Sort data in the ascending order Swap Rows and Columns - Swap all items present in the Rows deck with those present in the Columns deck and vice versa Refresh Data and Extracts - Pull in the latest data from your data source to refresh it or refresh your Extract from your Data Source.Īdd Worksheet - Add a new blank Worksheet to your WorkbookĪdd Dashboard - Add a new blank Dashboard to your WorkbookĬlear Worksheet - Clear the current Worksheetĭuplicate Sheet - Duplicate the current sheet with all of its Decks, Filters and settings Save - Save the current Visual Analytics WorkbookĬonnect to Data - Connect to a new Data Source and manage your currently connected Data Source Open - Open an existing Visual Analytics Workbook New - Launches a new Visual Analytics window The following table contains the toolbar icons and their descriptions You can also rearrange the decks of the Visual Analytics window by dragging their title bars into different locations. You can resize a Sheet's decks and views by locating their handles and dragging them. Each Sheet can display a Worksheet or a Dashboard (collection of Data Views from multiple Worksheets). A single Workbook can contain many Worksheets, each with its own tab displayed at the bottom of the workspace. Visual Analytics Studio is divided into the Toolbar (containing the Menu and Toolbar Buttons), the Data Sources (the Data Pane), Decks (where you drag data source Dimensions and Measures to make Data Views) and the Data View. Visualization: Learn how Visual Analytics' intelligent Visualization Menu can suggest and even generate charts for you based on what it detects in the Columns and Rows decks. ![]() ![]() The Visual Analytics Workspace: Understand the different areas of the tool and what they're for, including Worksheets and Dashboards.Ĭonnect to Data: Learn how to connect to Data Sources and how to generate Data Extracts.īuild Views: Learn how to drag and drop Dimensions and Measures to build a view, with examples of different Chart Types. Launching Visual Analytics: Learn how to launch Visual Analytics from within Aqua Data Studio. Work through some examples and build views after learning how to connect to data sources. See what the tool can do and explore the Visual Analytics Workspace to understand its environment and layout. This Wiki Book contains all of the Visual Analytics documentation. Visual Analytics lets you pull data from your Query Results into visualizations within Worksheets and Dashboards so you can save and share them with colleagues and customers. ![]() Welcome to Visual Analytics for Aqua Data Studio. A ruined colony is a dramatic tragedy, not a failure. 'RimWorld is a story generator, not a skill test. Have fun with the heat you might not be ready to take care of. But I don't recommend it, since it adds a new custom faction and you'll less likely to find them in your map mid-save.Ī: I don't use CE, please ask the CE bois instead. Well I got the mod just for you Introducing 'Kraltech Industries' This mod adds new mechanoids to fight and gestate called the mechanoid variants, new bosses to challenge which includes 3 new mech variant bosses and an ultra boss, and adds a custom humanoid spacer faction to interact or conquer (Good luck). Warhunter also forgot that it can become a big problem if you get a solar flare during a heat wave. If someone is overheating just draft them and throw them inside a bit. at all, and i dont get any or event that would. Before the patch that added passive coolers it was an RNG game over for tribes in many climates. ooookay so the last 3 game sive played i have had heatwave start a day or so after start and then. If there are, kindly tell me about it in the comments.Ī: Well, yes. Unless you modify the start, both tribes and new arrivals have options to counter heat wave (passive cooler and air conditioner respectively). If your freezer has temperature issues due to frequent visits, consider adding one more layer of airlock. I would love to grow around 1000 ibex and let them free at the same time, but the process getting there would be too tedious. I haven't encounter any compatibility problems as of yet. All coolers were set to -19, freezers were left undisturbed in the shown state for 8 hours. I guess the Rimworld engine starts to have too many pawns to handle, making the game laggy. It also adds new weapons and armor to craft, new buildings to build, new items to abuse, new incidents and quests to encounter, and a brand new story teller that could potentially ruin your play through. ![]() This mod adds new mechanoids to fight and gestate called the mechanoid variants, new bosses to challenge which includes 3 new mech variant bosses and an ultra boss, and adds a custom humanoid spacer faction to interact or conquer (Good luck). Are you a fan of killer robots? A fan of killer robots that can beat your ass senseless perhaps? Or better yet, are you a fan of spacer tech faction that sells expensive firepower, but can't afford it because you're poor as ♥♥♥♥? Well I got the mod just for you! Introducing "Kraltech Industries"!! ![]() Because jasper has so many varieties, there are meanings for each type.įor instance, yellow jasper meaning comes from the stone’s protective properties, offering inner strength, discernment, and clarity. The etymology and jasper name meaning comes from the Old French word “jaspre” which is derived from the Latin term “iaspidem,” both of which means “spotted or speckled stone.”Īnother jasper stone meaning you may have heard is “supreme nurturer,” a deserving name for one of the most precious healing stones. What does the jasper symbolize, and where does the name come from? Let’s take a look at the various jasper meanings next! Jasper Stone Meaning Additionally, almost all aspers have patterns, although they vastly differ in appearance and color. While jasper types vary across the board, there are uniting features, such as their chalcedony and quartz composition. “The formation of various kinds of silica like Agates, Jaspers, and Chalcedonies has been concluded that they originated from the influences of the weather, the dry, hot or the wet and the dry seasons, and sometimes meteoric impact into the earth and the environment.” In Author Marco Campos Venuti’s book, Genesis and Classification of Agates and Jaspers - a New theory, the Italian volcanologist and author of the Gemmologica Italiana passionately informs about the magnificent properties of Jasper and Agate stones. Treatments: None, heat treatment, or dyeingīecause there are so many jasper varieties, how can you identify the stone? Luminescence: Varies depending on different mineral impurities in jasper types While there are many jasper types, below, we’ll outline the stone’s characteristics that categorize it as jasper stone.Ĭolor: All colors, including green, red, orange, yellow, black, blue, and more.Ĭrystal structure: Microcrystalline, hexagonal For example, bloodstone is a type of jasper with red inclusions while bumblebee jasper comes in bright, happy hues of yellow, orange, and black. What color is jasper? Great question! Jasper gems come in endless varieties, but every type gets its name from its color. As a stone, jasper is relatively hard, ranking at 7 on the Mohs Hardness Scale, making it a dependable material for jasper jewelry. Jasper rock, crystal, and gemstone specimens contain tiny quartz crystals that gain color from trace mineral impurities, such as iron in red jasper. Jasper Specifications and Characteristics What gives jasper its coloring? To answer that question, let’s explore the gem’s characteristics. ![]() Known for their practical and industrial personalities, it’s not surprising that their zodiac stone is one of the most protective and grounding around. Jasper is the zodiac stone and Sun Sign for Virgo. But why choose only one color? Jasper stone colors are generally multi-colored with striking patterns.īecause of their beauty, bloodstone jasper makes for a personalized March birthstone gift. While most people are familiar with green jasper stone due to historical prevalence and biblical references, these gemstones come in all colors, including brown, yellow, red, orange, black, green, gray, and just about any color you can think of. There are many gemstones in the market, but few have such a vast and extensive history as jasper. There are many types of jasper, but the most common are Ocean Jaspers, produced by sedimentation deep in the ocean’s seafloor. ![]() Because of their intensely vibrant patterns and colors, jewelers and lapidaries most commonly fashion them into polished cabochons to highlight their uniqueness. Jasper stone is a member of the quartz mineral family, with silica compositional properties that give the stones an opaque appearance. ![]() We’ve got a lot to cover about the jasper stone, and we’re sharing everything you need to know in this comprehensive guide - from jasper types to meanings to history to uses to gemstone properties and value. Since antiquity, people have harnessed jasper properties for protection, spiritual enlightenment, and natural healing. Jasper is a form of microcrystalline quartz or chalcedony that’s been around for millennia. Matching its color diversity is the infinite patterns and combinations seen from gem to gem. What gemstone is as old as the earth itself? Jasper, of course! Jasper is a unique and versatile gemstone that comes in every color of the rainbow. ![]() Scenery is a free Mac App that will helps you convert your app screenshots into professional looking and real-life photographs. PlaceIt and Mockerie are other good services for adding device mockups to your screenshots but they requires a subscription. ![]() The tool produces very high-resolution screenshots and they offer device frames for the iPhone, iPad & iPad Mini, Windows Phone, TV screenshots and Android. You pick a device frame, upload the mobile screenshot image and the tool will generate multiple screenshot images of the same device but at different angles. ![]() MockuPhone is another useful web app for adding device frames to your mobile screenshots with a unique feature. You also have the option to add screen glare and depth (for perspective) to the generated screenshots. ![]() Device Art Generator includes templates for Android Wear and all Google Nexus devices. Drag the mobile screenshot image on to a device frame and it will quickly wrap that frame around your image. Google’s own Device Art Generator lets you quickly add vector device frames around screenshots of Android phones and tablets. You need to drag your app’s screenshot image on to a photograph and it will automatically get placed in the screen area of the mobile device perfectly aligned with the hardware frame pixel by pixel. These tools offers a collection of professional-quality photographs of mobile phones, tablets and computers placed in realistic settings. If you don’t have Photoshop, you can use web apps like Magic Mockups, Dunnnk and Frame to add photorealistic device frames to your mobile screenshots. PS:Dribbble users usually add the tag “freebies” or “free” to indicate that others can reuse their design(s) for personal and commercial use. Other than Dribbble, Deviant Art and Behance are also good places to discover high-quality hardware mockups for all popular mobile devices. Then use the Save for Web option to export the image in JPEG format. The Facebook design team too provides Handskit - photos of hands holding devices that you can use without restrictions.ĭownload and import the PSD file into Photoshop and then use the File -> Place command to place the screenshot image as a new layer over the device mockup. Realistic Device Mockups for Beautiful App ScreenshotsĪ layered photo editing tool like Adobe Photoshop (Win/Mac) or Pixelmator (Mac) makes it really easy for you to add hardware device frames to any screenshot image. Go to Dribbble and search for freebies PSD and you’ll find beautiful mockups for any mobile device. The device frames can be actual photographs so your screenshot images appear gorgeous and more realistic. This is important because people should be able to figure out whether a screenshot was captured on an iPhone or a Microsoft Lumia or a Google Nexus phone. That’s a raw screenshot saved in your camera roll but if you would like to use that image in your website, a presentation or even in your Apps Store listing, consider adding device frames. And in the case of Windows Phone, press and hold the Start and Power buttons at the same time to take a screenshot. Android users can press the Volume Down & Power button simultaneously to capture the screen. If you have an iPhone, press the Home & Sleep buttons and the screenshot image will be saved in the Photos app. Capturing screenshots on a mobile phone is easy. The truck was filled with iPhone X devices that were being shipped to the store.Īs for the theft, the UPS driver had locked the cargo area after parking outside the Stonestown Galleria mall in the southwest Lakeside neighborhood of San Francisco, according to the police report. Pacific Time, according to police report details shared by CNET. Three men in hoodies driving a white Dodge van broke into a UPS truck outside of the Stonestown location on Wednesday morning between 11:15 and 11:30 a.m. Your feedback is valued! Express your opinions in the box provided below.Just hours ahead of when the iPhone X is set to be available in the United States, thieves made off with more than 300 iPhone X models that were snatched yesterday afternoon from the Stonestown Apple Store in San Francisco, California. If you have found any discrepancies or mistakes in the address info or business times for Target in Stonestown, San Francisco, CA, please utilize this form to report a problem. Our site's intention is to deliver you with the most accurate information as possible. In this spot you can also find Target, Trader Joe’s, McDonald's, Chase Bank, Apple, Panda Express and a few others. Visit Stonestown Galleria today for other appealing stores and great offers. To get further information about seasonal business hours for Target Stonestown, San Francisco, CA, go to the official site or phone the direct line at 4156802914. For year 2023 these revisions include Xmas Day, Boxing Day, Easter Sunday or Labor Day. Holidays may bring about revisions to the common hours of operation for Target in Stonestown, San Francisco, CA. Serramonte Center, Daly City, CA (3.89 miles away)įor more Target visit this following page for an entire index of locations near San Francisco. ![]() Westlake, Daly City, CA (1.84 miles away). ![]() You are never far from a second Target! You can find other branches nearby: Target Locations Nearby San Francisco, CAĪt present, Target runs 3 locations in San Francisco, California. ![]() If traveling by foot you'll find Habitat Garden, Merced Branch Library, HSS Courtyard, Cox Stadium, Maloney Field and Stonestown Galleria Mall. There are a number of light rails that run to Stonestown/Lakeside/Winston Station (580 ft), Right of Way/Eucalyptus Dr Station (1820 ft) and San Francisco State University Station (1900 ft away). The lines, which stop here: Dublin/ Pleasanton– Daly City, Richmond– Daly City/ Millbrae, Warm Springs/South Fremont– Daly City and Pittsburg/Bay Point–SFO/Millbrae. Nearby Daly City Station (1.55 mi), Balboa Park Station (1.83 mi) and Glen Park Station (2.60 mi away). The bus stops are located conveniently at 19Th Avenue & Buckingham Way, 20Th Avenue & Winston Drive, 95 Buckingham Way and Stonestown. Those using GPS systems can enter 285 Winston Drive, San Francisco, CA 94132. Just a 1 minute trip from Buckingham Way, 19th Avenue, Denslowe Drive and Stonecrest Drive a 5 minute drive from Lake Merced Boulevard, Junipero Serra Boulevard and Sloat Boulevard and a 9 minute drive time from Ocean Avenue and Portola Drive. You will find Target currently situated right near the intersection of Winston Drive and 20th Avenue, in Lakeshore, San Francisco, at Stonestown Galleria. ![]() is designed to run in four deployment modelsĪll microservices run off-site in the cloud and may shared with other customers. For example, a service like the tcp/ipĭriver must obviously run with low latency close to the automation systems layer whereas and UI services may easily run off-side. This mainly depends on the quality requirements of the project. In the cloud or on premise customer side. Deployment ScenariosĪ typical customer project built with is usually a composition of microservices to fulfill the functional requirements. Technologyīuilt their own product on top of to fully control their warehouses on their own. Non-functional requirements like the systems availability, performance and reliability are first-class requirements, too. The WMS part is connected to ERP systems whereas the Transport Management System controls field controllers, like Raspberry Pi consists of a Warehouse Management part (the WMS domain), the WCS (TMS domain)Īnd connectors to other systems. This strives for extendabilityĪnd flexibility of the software to realize features efficiently. Almost all customer projects in the intralogistics domain bring their own specific functional requirements. Integration with a varying number of enterprise information systems (like ERP) and field controllers (e.g. Over the years even customers ramped up DevOps teams to customize and operate in their own way to reduce cost and time-to-market. ![]() is a software project to build modern warehouse management systems with. Kitsu is also avaiable as a managed cloud-hosted service provided by CGWire, with prices ranging from €99/month (around $112/month) for up to 10 users, to €999/month ($1,130/month) for up to 150 users.An open source software to build intralogistic projects with. You can find instructions for self-hosting the software here. Source code for Kitsu and Zou is available under an AGPL licence Gazu is available under a LGPL licence. Those to have done so so far include the VES Award-winning Unit Image, along with commercials and 3D animation studio Cube Creative and character outsourcing studio Karlab.ĬGWire’s key staff also have backgrounds in production management themselves.ĬEO Frank Rousseau used to work for HD3D, developer of production-tracking system ArtForge, while product manager Gwenaëlle Dupré used to be head of production at Unit Image. Kitsu is also being developed in collaboration with artists working on real productions, since CGWire has the unusual development model of getting local studios to sponsor new features. The assets shown are from open short Caminandes.ĭeveloped with input from leading local production facilities Kitsu includes shot review and annotation capabilities. The system can also be used for asset reviews – images, movies and OBJ files can be reviewed directly in the browser – with simple in-picture annotation capabilities.įor pipeline integration, Kitsu comes with its own HTTP API, Zou, and Python client, Gazu, for writing custom tools or plugins for DCC software. Artists can use the system to view or check off assigned tasks, or fill in timesheets. Production managers can set up assets, shots, breakdowns, and assign tasks to individual artists. The feature set is pretty much what you would expect in a solution of this type, if currently somewhat bare-bones, Kitsu still being officially on its 0.8 release. It has a clean, minimal interface, but is designed to scale to commercial production work, particularly broadcast production: the option to group shots into episodes is provided natively. The system, which is available open-source or as a commercial cloud-hosted solution, is being developed in collaboration with some of France’s leading VFX facilities.Ī streamlined production tracking tool aimed at smaller studiosĪ JavaScript-based web application – it’s based on the Vue.js framework – Kitsu is intended to be a streamlined, lightweight production-tracking and communication tool. ![]() Posted by Jim Thacker Check out open-source production-tracking tool Kitsuįrench start-up CGWire has launched Kitsu, a new production-tracking tool aimed at small-to-mid-size studios that it describes as “better than Excel, cheaper than Shotgun”. ![]() ![]() I had bought a few boxes to flip and now I'm sitting on them. If you were going to part a Box out and sell the valuable cards, assuming a handling fee of 15% and only selling cards worth 10$ or more at current MARKET prices, you would have a gross total sales of: $448.89 +/- $110.82 SDĮven at the current box prices of $300 its still a bargain! Furthermore according to MTG Goldfish price ticker, this set has already bottomed out and is climbing again. If you were going to part a Box out and sell the valuable cards, assuming a handling fee of 15% and only selling cards worth 4$ or more at current MARKET prices, you would have a gross total sales of: $489.99 +/- $118.58 SD The Expected Value of a Box (not including uncommon and common that aren't foils) is: $679.07 +/- $133.92 SD The Expected Value of a Box, considering only cards worth $4 or more is: $612.49 +/- $148.23 SD The Expected Value of a Box, considering only cards worth $10 or more is: $561.12 +/- $138.52 SD The value is BETTER than the article which was guessing at $500 and didn't include the variances (SD = Standard Deviation). I did it as a series of simulation models where I simulated 36 packs of cards within boxes to get box values and did 1000 boxes per run to get a mean and standard deviation on expected box value. I took the mtg goldfish article on expected value for Time Spiral Remastered ( ), used the reported probabilities of each card type, and recalculated the box values with the prices for regular foils and time shifted border foils with current MARKET prices as of today on MTG Stocks. This is reposted from another thread after a commenter told me to start a new one to share. I'll try to figure out if there is an issue and repost, but it seems clear that the lottery aspect of the foil old border cards and their expected value which is huge part of the potential box value is a big X factor in getting this correct. Card prices are swinging wildly and are all over the price. I spent some time last night going over this with one helpful redditor, not sure if/where there is an error but I did notice very very large differences in market prices for foil cards between their list and mine. # UPDATE: A number of folks have suggested that this distribution is higher than it ought to be and that it doesn't reflect personal experience. No threads asking what to do with your cards or money Single questions about cards/money/selling advice should be asked in the stickied threads posted every Mo/We/Fr. "Buyer beware" posts require submitting proof with identifying info removed. SCD, Video and card photo posts must include a brief summary. No Low Effort Posts: If you are requesting research, or the answer to your question can be found through public knowledge, find it yourself and post it. No spam, flaming, brigading, harassing.Īll posts must be financially related / No counterfeit authentication requests. Otherwise, request your post get approved manually by a moderator.įollow Redditiquette. Friday - Things to look out for this weekend!įor submissions, users must have at least 500 combined Karma to post.Wednesday - Weekly Ask MTGFinance Anything.Monday - Weekend Wrapup! What was real and what was a trap. Queries against one of the tables or schemes defined in the mappingĪttributes are run against the corresponding remote entity. The following example sets a simple comment that identifies each query sent by Variables from the Trino cluster with the comment, use the Information is available in the logs of the datasource. The comment can provide more context about the query. $TRACE_TOKEN: The trace token configured with the client tool. $SOURCE: The identifier of the client tool used to submit the query, for $USER: The name of the user who submits the query to Trino. The format of thisĬomment can contain any characters and the following metadata: The optional parameter ment-format allows you to configure a SQLĬomment that is sent to the datasource with each query. However, it can also increase latency for some queries. Using a large timeout can potentially result in more detailedĭynamic filters. Maximum duration for which Trino waits for dynamicįilters to be collected from the build side of joins before starting a Push down dynamic filters into JDBC queries. Maximum number of statements in a batched execution. ![]() Maximum number of objects stored in the metadata cache. Defaults to 0s (caching disabled).Ĭache the fact that metadata, including table and column statistics, isĭuration for which schema metadata is cached.ĭefaults to the value of metadata.cache-ttl.ĭuration for which table metadata is cached.ĭuration for which tables statistics are cached. The duration value defaults to 0sĭuration for which metadata, including table andĬolumn statistics, is cached. Trino to disambiguate between schemas and tables with similar names inĬ-periodįrequency with which Trino checks the name matching configuration fileįor changes. Path to a name mapping configuration file in JSON format that allows Defaults to false.ĭuration for which case insensitive schema and tableĬnfig-file Support case insensitive schema and table names. The following table describes general catalog configuration properties for the ![]() ForĮxample, if you name the property file sales.properties, TrinoĬreates a catalog named sales using the configured connector. With a different name, making sure it ends in. MySQL servers, simply add another properties file to etc/catalog You can have as many catalogs as you need, so if you have additional Password for the password key store entity. Name of the key store entity to use as the password. ![]() Password for the user name key store entity. Name of the key store entity to use as the user name. The location of the Java Keystore file, from which to read credentials.įile format of the keystore file, for example JKS or PEM. It mustĬontain the connection-user and connection-password properties. Location of the properties file where credentials are present. Name of the extra credentials property, whose value to use as the Name of the extra credentials property, whose value to use as the user The following table describes configuration properties You can use secrets to avoid storing sensitive Inline, in the connector configuration fileĪs extra credentials set when connecting to Trino The connector can provide credentials for the data source connection You can set the sslMode parameter in the catalog configuration file byĪppending it to the connection-url configuration property:Ĭonnection-url = jdbc:mysql://:3306/?sslMode=REQUIREDįor more information on TLS configuration options, see the MySQL JDBC securityĭocumentation. You canĪlso set this parameter to REQUIRED which causes the connection to fail if PREFERRED which secures the connection if enabled by the server. Parameter to secure the connection with TLS. Source by appending a parameter to the JDBC connection string set in theĬonnection-url catalog configuration property.įor example, with version 8.0 of MySQL Connector/J, use the sslMode If you have TLS configured with a globally-trusted certificate installed on yourĭata source, you can enable TLS between your cluster and the data ![]() Use secrets to avoid actual values in the catalog The connection-user and connection-password are typically required andĭetermine the user credentials for the connection, often a service user. Connection-url=jdbc:mysql://:3306?sslMode=REQUIRED AEMs are also alkaline by definition, allowing for cheaper cell components because of the reduced corrosiveness. AEMFCs operate in the same temperature range but can potentially be independent of Pt-group metal-based catalysts. However, their dependency on Pt has necessitated intensified research on anion exchange membrane fuel cells (AEMFCs). 1–4 In the case of portable applications such as in the automotive industry, proton exchange membrane fuel cells (PEMFCs) offer the highest power density, efficiency, and durability. Silence and quick refuelling are especially attractive for automobile use. Not only is the system energy efficient, with no production of CO 2, but the technology also has the added benefits of quietness and rapid refuelling. Fuel cell technology is considered an integral part of an overall effective solution to this problem. Introduction With the growing urgency to address global warming, curbing emissions from human activity is becoming increasingly necessary. The availability of this technique is an essential prerequisite in improving the ionic conductivity and effectively solving the persisting durability challenge facing AEMFCs, thus hastening the possibility of mass commercialisation of fuel cells. These results confirm the viability of micro-Raman spectroscopy in studying the various water-related species in AEMs. All the hydrogen-bonded OH species increased steadily with increasing humidity, while the CH and non-H-bonded OH remained relatively constant. The OH stretching band was deconvoluted into nine unique Gaussian bands. Spectra of pure water, alkaline solutions, and calculations based on density functional theory were used to identify the water species in the AEM. In this paper, different water species inside an anion exchange membrane (AEM), QPAF-4, developed at the University of Yamanashi, were studied for the first time using micro-Raman spectroscopy. Water characterization inside the membrane is one factor that significantly influences the performance of AEMFCs. Unlike PEMFCs, AEMFCs have demonstrated the capability to operate independently of Pt group metal-based catalysts. Using a spectroscope, identify a reactive metal present in fluoroscent lights.Anion exchange membrane fuel cells (AEMFCs) hold the key to future mass commercialisation of fuel cell technology, even though currently, AEMFCs perform less optimally than proton exchange membrane fuel cells (PEMFCs). Using a spectroscope, identify a hazardous element present in fluoroscent lights. Click to see some examples of emission spectra. Look at the flame through a spectroscope to reveal the unique emission spectrum formed for each element. The colour of the flame may not be sufficient to distinguish between the different elements such as strontium and lithium. View the video of the sodium chloride flame test. On the right is the flame for sodium chloride On the right is the flame for strontium chloride View the video of the copper chloride flame test On the right is the flame for copper chloride. View the video of the lithium chloride flame test On the right is the flame for lithium chloride. You may need to turn the light off in the classroom.Ī method that is less messy and provides a long lasting coloured flame can be conducted usinga 2 litre soft drink bottle and a bunsen burner. Spray each solution into the flame and record its colour. solutions of barium chloride,copper chloride, sodium chloride, strontium chloride and calcium chloride. The combination of all these lines gives the metal ion a unique colour during the flame test. An emission spectrum is a set of coloured lines that correspond to the energy the electron has released at each stage of its fall back to its original state. The result of all these jumps is to produce what is called an emission spectrum. This would release a certain amount of energy, relative to the jump, which would be seen as light of a particular colour. For example, an electron that has been excited from the 2p subshell to the 6s subsell can fall back in one go or via another subshell, such as the 4d. Electrons tend to lose the energy they have absorbed by falling back to where they were before. Now that the electrons are at a more energetically unstable state energy must be lost. When the ion absorbs energy, electrons gain energy and jump into any of a number of empty orbitals at higher levels such as the 5s or 7p or 4d, depending on how much energy the electron has absorbed, as shown on the right Metal atoms give off distinct colours of light.įor example, a sodium ion in an unexcited state has the structure 1s 22s 22p 6. When the electron returns to its original position it gives off the energy it absorbed in the form of light. When a metal atom is strongly heated, its electrons absorb the heat energy and jump to a higher energy level. |
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